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Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

《化学科学与工程前沿(英文)》 2019年 第13卷 第1期   页码 164-170 doi: 10.1007/s11705-018-1755-2

摘要:

Chalcogenide nanostructured semiconductor, copper sulfide (CuS) was prepared from copper and sulfur powders in stoichiometric ratio by a simple, fast, and convenient one-step mechanochemical synthesis after 40 min of milling in an industrial eccentric vibratory mill. The kinetics of the mechanochemical synthesis and the influence of the physical properties of two Cu powder precursor types on the kinetics were studied. The crystal structure, physical properties, and morphology of the product were characterized by X-ray diffraction (XRD), the specific surface area measurements, particle size distribution and scanning electron microscopy. The XRD analysis confirmed the hexagonal crystal structure of the product-CuS (covellite) with the average size of the crystallites 11 nm. The scanning electron microscopy analysis has revealed that the agglomerated grains have a plate-like structure composed of CuS nanoparticles. The thermal analysis was performed to investigate the thermal stability of the mechanochemically synthesized CuS. The optical properties were studied using UV-Vis and photoluminescence spectroscopy. The determined optical band gap energy 1.80 eV responds to the value of the bulk CuS, because of agglomerated nanoparticles. In addition, a mechanism of CuS mechanochemical reaction was proposed, and the verification of CuS commercial production was performed.

关键词: copper sulfide     industrial mechanochemical synthesis     thermal analysis     optical properties    

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

《化学科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 265-268 doi: 10.1007/s11705-008-0054-8

摘要: The polymer stabilized liquid crystal (PSLC) film is a relatively novel electro-optical material, which is generally obtained by dissolving a small amount of a bifunctional photoreactive monomer in a low molecular mass liquid crystal. In this paper, the PSLC films were prepared with photoreactive biphenyl methacrylate monomers by photopolymerization induced phase separation. The effects of liquid crystal concentration, curing time, monomer structures and alignment layer on the electro-optical properties of PSLC films were investigated. The results show that the transmittance in the OFF state () increased with the liquid crystal concentration, but the driving voltage decreased. was also influenced by the curing time. Furthermore, when polyimide was used as alignment layer, the films prepared from the bifunctional monomer shows a higher T, while those from the single functional monomer exhibited a deformed electro-optical curve due to the unsteady polymer networks.

Development of surface reconstruction algorithms for optical interferometric measurement

Dongxu WU, Fengzhou FANG

《机械工程前沿(英文)》 2021年 第16卷 第1期   页码 1-31 doi: 10.1007/s11465-020-0602-6

摘要: Optical interferometry is a powerful tool for measuring and characterizing areal surface topography in precision manufacturing. A variety of instruments based on optical interferometry have been developed to meet the measurement needs in various applications, but the existing techniques are simply not enough to meet the ever-increasing requirements in terms of accuracy, speed, robustness, and dynamic range, especially in on-line or on-machine conditions. This paper provides an in-depth perspective of surface topography reconstruction for optical interferometric measurements. Principles, configurations, and applications of typical optical interferometers with different capabilities and limitations are presented. Theoretical background and recent advances of fringe analysis algorithms, including coherence peak sensing and phase-shifting algorithm, are summarized. The new developments in measurement accuracy and repeatability, noise resistance, self-calibration ability, and computational efficiency are discussed. This paper also presents the new challenges that optical interferometry techniques are facing in surface topography measurement. To address these challenges, advanced techniques in image stitching, on-machine measurement, intelligent sampling, parallel computing, and deep learning are explored to improve the functional performance of optical interferometry in future manufacturing metrology.

关键词: surface topography     measurement     optical interferometry     coherence envelope     phase-shifting algorithm    

Precision glass molding: Toward an optimal fabrication of optical lenses

Liangchi ZHANG,Weidong LIU

《机械工程前沿(英文)》 2017年 第12卷 第1期   页码 3-17 doi: 10.1007/s11465-017-0408-3

摘要:

It is costly and time consuming to use machining processes, such as grinding, polishing and lapping, to produce optical glass lenses with complex features. Precision glass molding (PGM) has thus been developed to realize an efficient manufacture of such optical components in a single step. However, PGM faces various technical challenges. For example, a PGM process must be carried out within the super-cooled region of optical glass above its glass transition temperature, in which the material has an unstable non-equilibrium structure. Within a narrow window of allowable temperature variation, the glass viscosity can change from 105 to 1012 Pa·s due to the kinetic fragility of the super-cooled liquid. This makes a PGM process sensitive to its molding temperature. In addition, because of the structural relaxation in this temperature window, the atomic structure that governs the material properties is strongly dependent on time and thermal history. Such complexity often leads to residual stresses and shape distortion in a lens molded, causing unexpected changes in density and refractive index. This review will discuss some of the central issues in PGM processes and provide a method based on a manufacturing chain consideration from mold material selection, property and deformation characterization of optical glass to process optimization. The realization of such optimization is a necessary step for the Industry 4.0 of PGM.

关键词: precision glass molding     optical lens     constitutive modeling     optimization     manufacturing chain     Industry 4.0    

国外光纤光纤带和带状光缆技术的最新发展

刘良炎

《中国工程科学》 2001年 第3卷 第9期   页码 86-94

摘要:

综合介绍了近年国外关于低衰耗的色散补偿光纤,非零色散位移光纤,用于恶劣环境的碳涂覆和氮化硅涂覆光纤的研究;光纤带制造技术包括光纤带的结构、涂层、性能、生产工艺,大芯数光纤带状光缆包括层绞式松管、中心松管式、骨架式、干缆芯带状光缆的设计制造技术的最新进展。

关键词: 光纤通信     低衰耗光纤     光纤带     光纤带状光缆    

成像光学工程面临的光学问题

潘君骅

《中国工程科学》 2000年 第2卷 第3期   页码 32-35

摘要:

文章简单论述了现代成像光学主要领域的情况,指出非球面反射系统是发展的必然趋势。讨论了加工与检验方面的基本情况及应着重深人研究的问题。对镜坯材料也提了一点看法。

关键词: 成像光学     非球面反射镜     光学设计     光学加工与检验    

Effects of critical geometric parameters on the optical performance of a conical cavity receiver

Hu XIAO, Yanping ZHANG, Cong YOU, Chongzhe ZOU, Quentin FALCOZ

《能源前沿(英文)》 2019年 第13卷 第4期   页码 673-683 doi: 10.1007/s11708-019-0630-2

摘要: The optical performance of a receiver has a great influence on the efficiency and stability of a solar thermal power system. Most of the literature focuses on the optical performance of receivers with different geometric shapes, but less research is conducted on the effects of critical geometric parameters. In this paper, the commercial software TracePro was used to investigate the effects of some factors on a conical cavity receiver, such as the conical angle, the number of loops of the helical tube, and the distance between the focal point of the collector and the aperture. These factors affect the optical efficiency, the maximum heat flux density, and the light distribution in the conical cavity. The optical performance of the conical receiver was studied and analyzed using the Monte Carlo ray tracing method. To make a reliable simulation, the helical tube was attached to the inner wall of the cavity in the proposed model. The results showed that the amount of light rays reaching the helical tube increases with the increasing of the conical angle, while the optical efficiency decreases and the maximum heat flux density increases. The increase in the number of loops contributed to an increase in the optical efficiency and a uniform light distribution. The conical cavity receiver had an optimal optical performance when the focal point of the collector was near the aperture.

关键词: parabolic collector     conical cavity receiver     critical geometric parameters     optical performance    

Recent advancements in optical microstructure fabrication through glass molding process

Tianfeng ZHOU,Xiaohua LIU,Zhiqiang LIANG,Yang LIU,Jiaqing XIE,Xibin WANG

《机械工程前沿(英文)》 2017年 第12卷 第1期   页码 46-65 doi: 10.1007/s11465-017-0425-2

摘要:

Optical microstructures are increasingly applied in several fields, such as optical systems, precision measurement, and microfluid chips. Microstructures include microgrooves, microprisms, and microlenses. This paper presents an overview of optical microstructure fabrication through glass molding and highlights the applications of optical microstructures in mold fabrication and glass molding. The glass-mold interface friction and adhesion are also discussed. Moreover, the latest advancements in glass molding technologies are detailed, including new mold materials and their fabrication methods, viscoelastic constitutive modeling of glass, and microstructure molding process, as well as ultrasonic vibration-assisted molding technology.

关键词: optical microstructure     microgroove     microlens     glass molding process     single-point diamond cutting    

真空光镊技术综述 Special Feature on Precision Measurement and Inst

Nan LI, Xun-min ZHU, Wen-qiang LI, Zhen-hai FU, Meng-zhu HU, Hui-zhu HU

《信息与电子工程前沿(英文)》 2019年 第20卷 第5期   页码 655-673 doi: 10.1631/FITEE.1900095

摘要: 光镊技术自上世纪七十年代由阿瑟·阿什金开创以来,作为捕获和操纵中性粒子的通用工具,已在分子生物学、纳米技术和实验物理学等领域得到广泛研究和应用。基于光镊技术的传感与精密测量系统,通过激光束悬浮传感单元,而非与装置固连,相比传统固态传感器,无机械耗散。此外,与液体或空气介质中的光镊系统不同,在真空中运作的光镊系统可实现传感单元与环境的完全隔离。基于上述优势,基础物理学和应用物理学领域科学家对真空光镊开展了大量研究。本文回顾了真空光镊技术的基本概念和发展历史,帮助读者全面了解该领域。

关键词: 光镊;真空光阱;激光冷却    

光传送网中光监控通道信号Q值在线监测技术

唐勇,孙小菡,张明德,丁东

《中国工程科学》 2001年 第3卷 第12期   页码 71-75

摘要:

提出了一种带有光监控通道(OSC)子系统的光传送网(OTN)分层结构模型,分析了OSC中的信号特点,指出OSC信号质量决定了运行、管理和维护(OAM)信号的可靠性。依据Q值与误码率(BER)的一一对应关系,提出了一种可在线监测OSC信号Q值的方案,并基于数字信号处理芯片(DSP)技术设计了监测模块,实现了OSC信号在线Q值监测。

关键词: 光传送网(OTN)     光监控通道(OSC)     运行、管理和维护(OAM)     Q值监测    

New computational treatment of optical wave propagation in lossywaveguides

Jian-xin ZHU,Guan-jie WANG

《信息与电子工程前沿(英文)》 2015年 第16卷 第8期   页码 646-653 doi: 10.1631/FITEE.1400406

摘要: In this paper, the optical wave propagation in lossy waveguides is described by the Helmholtz equation with the complex refractive-index, and the Chebyshev pseudospectral method is used to discretize the transverse operator of the equation. Meanwhile, an operator marching method, a one-way re-formulation based on the Dirichletto-Neumann (DtN) map, is improved to solve the equation. Numerical examples show that our treatment is more efficient.

关键词: Adjoint operator     Orthogonal     Chebyshev     Pseudospectral method     Dirichlet-to-Neumann map    

光纤通信技术发展现状与展望

谈仲纬,吕超

《中国工程科学》 2020年 第22卷 第3期   页码 100-107 doi: 10.15302/J-SSCAE-2020.03.016

摘要:

作为激光技术的重要应用,光纤通信技术是搭建现代通信网络的重要桥梁。随着物联网、大数据、云计算、虚拟现实和人工智能等新兴技术的涌现,信息传递需求与日俱增,这对光纤通信技术的发展提出了更高要求。本文在系统梳理光纤通信技术国内外发展现状的基础上,分析了在具体场景应用中面临的问题与挑战,研判了未来光纤通信技术发展的方向。经研究分析,激光通信技术在超大容量光纤通信系统中面临的挑战可从发射功率增加、光放大器带宽增加、低传输损耗光纤以及空分复用相关技术研究等方面入手探讨解决思路;同时结合现实应用情况,本文对面向其他场景的光纤通信系统成本困境的解决进行了思考。总体而言,光纤通信技术将朝着超大容量、智能化、集成化的方向不断演进,未来期望可以实现智能化网络参数监测和超长距离、超大容量信息传输,并且随着集成技术和光通信器件的不断进步,必将推动整个光纤通信行业的高性能、低成本发展。

关键词: 光纤通信     光网络     超大容量     集成     智能化    

Smart optical-fiber structure monitoring based on granular computing

Guan LU, Dakai LIANG,

《机械工程前沿(英文)》 2009年 第4卷 第4期   页码 462-465 doi: 10.1007/s11465-009-0073-2

摘要: Using an optic fiber self-diagnosing system in health monitoring has become an important direction of smart materials and structure research. The buried optic fiber sensor can be used to test the parameters of the composite material. The granular computing method can reach the requirement of damage detection by analyzing digital signals and character signals of the smart structure at the same time. The paper investigates an optic fiber smart layer and presents a method for realizing optic fiber smart structure monitoring and damage detection by using granular computing. After the analysis, it is presumed that optic fiber smart structure monitoring based on granular computation can identify the damage from complex signals.

关键词: smart material and structure     GrC     optical fiber sensor     rough set     clustering algorithm    

A novel decoupling approach to an integrated optical-fiber proximity sensor for robots

LIU Guixiong, LI Xiani

《机械工程前沿(英文)》 2007年 第2卷 第2期   页码 164-167 doi: 10.1007/s11465-007-0027-5

摘要: The structure and the working principle of a self-compensational integrated optical-fiber proximity sensor that detects distance and orientation are introduced in this paper. The corresponding decoupling approach to the sensor is presented on the basis of multiscale characteristics. The decoupling process can be divided into two parts: classifying the information on the basis of the multiscale degree and solving the coupling equation via the computational approximation methods with different precisions. Finally, the principle, the physical meaning, and the implementation process of the approach are discussed. They indicate that the proposed approach is real-time and accurate, and can be applied to other similar circumstances.

关键词: multiscale     different     self-compensational integrated     information     implementation    

Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

《化学科学与工程前沿(英文)》 2020年 第14卷 第1期   页码 19-27 doi: 10.1007/s11705-019-1888-y

摘要: We report here a water-soluble metal cation sensor system based on the as-prepared or reduced form of an expanded porphyrin, texaphyrin. Upon metal complexation, a change in the redox state of the ligand occurs that is accompanied by a color change from red to green. Although long employed for synthesis in organic media, we have now found that this complexation-driven redox behavior may be used to achieve the naked eye detectable colorimetric sensing of several number of less-common metal ions in aqueous media. Exposure to In(III), Hg(II), Cd(II), Mn(II), Bi(III), Co(II), and Pb(II) cations leads to a colorimetric response within 10 min. This process is selective for Hg(II) under conditions of competitive analysis. Furthermore, among the subset of response-producing cations, In(III) proved unique in giving rise to a ratiometric change in the ligand-based fluorescence features, including an overall increase in intensity. The cation selectivity observed in aqueous media stands in contrast to what is seen in organic solvents, where a wide range of texaphyrin metal complexes may be prepared. The formation of metal cation complexes under the present aqueous conditions was confirmed by reversed phase high-performance liquid chromatography, ultra-violet-visible absorption and fluorescence spectroscopies, and high-resolution mass spectrometry.

关键词: texaphyrin     fluorescent sensor     ion-sensing     indium     mercury    

标题 作者 时间 类型 操作

Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

期刊论文

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

期刊论文

Development of surface reconstruction algorithms for optical interferometric measurement

Dongxu WU, Fengzhou FANG

期刊论文

Precision glass molding: Toward an optimal fabrication of optical lenses

Liangchi ZHANG,Weidong LIU

期刊论文

国外光纤光纤带和带状光缆技术的最新发展

刘良炎

期刊论文

成像光学工程面临的光学问题

潘君骅

期刊论文

Effects of critical geometric parameters on the optical performance of a conical cavity receiver

Hu XIAO, Yanping ZHANG, Cong YOU, Chongzhe ZOU, Quentin FALCOZ

期刊论文

Recent advancements in optical microstructure fabrication through glass molding process

Tianfeng ZHOU,Xiaohua LIU,Zhiqiang LIANG,Yang LIU,Jiaqing XIE,Xibin WANG

期刊论文

真空光镊技术综述

Nan LI, Xun-min ZHU, Wen-qiang LI, Zhen-hai FU, Meng-zhu HU, Hui-zhu HU

期刊论文

光传送网中光监控通道信号Q值在线监测技术

唐勇,孙小菡,张明德,丁东

期刊论文

New computational treatment of optical wave propagation in lossywaveguides

Jian-xin ZHU,Guan-jie WANG

期刊论文

光纤通信技术发展现状与展望

谈仲纬,吕超

期刊论文

Smart optical-fiber structure monitoring based on granular computing

Guan LU, Dakai LIANG,

期刊论文

A novel decoupling approach to an integrated optical-fiber proximity sensor for robots

LIU Guixiong, LI Xiani

期刊论文

Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

期刊论文